铝金属化纸制备工艺的专利技术发展

通过对铝金属化纸领域专利技术的收集、分析、标引,介绍了铝金属化纸的制备方法及种类,包括铝粉涂布、铝箔纸以及可降解回收的真空镀铝纸等;并对其专利申请量、区域分布以及渡铝技术进行了分析,同时对各技术的发展历程和改进情况进行了梳理归纳。     

High‐performance printable paper‐like composites derived from plastic flexible film wastes

Owing to lack of proper recycling methods, plastic flexible film wastes are usually directly discarded or incinerated, which brings about severe environmental pollution. Therefore, converting plastic wastes into value‐added products has received more and more attention in recent years. In this work, paper‐like composites derived from plastic flexible film wastes were prepared via the thermally induced phase separation method by adding polyethylene‐graft‐maleic anhydride (PE‐g‐MAH) as a compatibilizer and fumed silica as an additive. The resulting paper‐like composites were characterized by SEM and infrared spectroscopy. Other properties such as mechanical properties, thermal properties, whiteness, printability and adsorption performance were also tested in detail. It was found that remarkable enhancements in mechanical, thermal and printable properties of the paper‐like composites were obtained when nano‐SiO₂ loading was 2.5–3 wt%. Uniformly distributed holes that can endow good printability by providing space for ink or other functional molecules were observed by using SEM. Furthermore, the CIE whiteness value of the resulting composites can reach 91.6%–96.7% on adding nano‐SiO₂. Additionally, the paper‐like composites integrating nano‐SiO₂ and PE‐g‐MAH exhibited good solid ink affinity and high water or oil adsorption capacity. Thus, according to this research, high‐performance printable paper‐like composites used as major components of multifunctional papers can be prepared based on plastic flexible film wastes. © 2019 Society of Chemical Industry     

Reduction of chlorophenols and sludge management from paper industry wastewater using electrocoagulation process

ABSTRACT

In this study, electrocoagulation (EC) was used to determine the optimum conditions on the basis of maximum chemical oxygen demand (COD) and color removal. At the optimum conditions chlorophenols (CPs), biological oxygen demand and total organic carbon (TOC) were determined. The biodegradability of wastewater was increased significantly with 63% COD, 98% color, 61% TOC and overall 65.51% reductions in CPs. Further, the electro-coagulated sludge was characterized by using different analytical techniques to assist the physicochemical and elemental phases, to find-out better management option, reusability for plant growth and safe disposal. Additionally, aluminum content (70.62%) was successfully recovered from sludge.     

纸芯片-敞开式质谱法分析减肥保健品的3种常见非法添加剂

目的 建立纸芯片与敞开式质谱联合法检测减肥保健品中3种常见非法添加剂的分析技术。方法 依据酸刻蚀法制备通道型纸芯片, 分别考察纸芯片的几何通道尺寸、不同比例有机喷雾溶剂所需的通道疏水坝宽度和喷雾电压对目标物的分析响应影响。将纸芯片与敞开式质谱联合, 分析减肥保健品中西布曲明、安非他酮和氟西汀的成分。结果 在正离子模式和3.5 kV电压下, 以甲醇/水为溶剂, 3种目标物在0.25~50.00 μg/mL表现出良好的线性关系, r2均大于0.99, 检出限为0.1 μg/mL, 回收率为89.9%~107.4%, 3种目标物在纸芯片喷雾纸上的相对强度与普通三角形喷雾纸增强了1.11~2.15倍, 线性关系也略有提高, 且检出限降低了2.75~3.5倍。25批次的实际样品中有19批次样品检测出了1种或多种违禁添加剂成分。结论 纸芯片结合敞开式质谱法可用于减肥类保健品中违禁添加剂的快速筛查手段。     

Fabrication and characterization of MnO2 based composite sheets for development of flexible energy storage electrodes

Development of cost efficient, flexible and light weight paper electrodes for high-tech applications is high in demand in era of modern disposable technology. In this study α-MnO₂ nanorods were fabricated through hydrothermal method by varying growth time and further combined with lignocelluloses fibers extracted from self growing plant, Monochoria Vaginalis. Crystal structure, morphology and thermal properties of MnO₂ nanorods were characterized by X. Ray Diffraction (XRD), Field Emission Scanning Electron Microscope (FESEM) and Thermogravimetric Analysis (TGA), respectively. FESEM image analysis revealed the highest aspect ratio of 48.016 for 4?h treated MnO₂ sample and high purity level was confirmed by XRD. MnO₂ sample with high aspect ratio, relatively pure and larger yield was selected for incorporation of lignocelluloses fibers to fabricate flexible, light-weight and environmentally safe LC/MnO₂ composite paper sheet. Furthermore, LC/MnO₂ composite sheet was employed as working electrode in 2?M sodium sulfate electrolyte for cyclic voltammetry measurements. Presented LC/MnO₂ composite sheet revealed specific capacitances 117, 59, 39, 25 and 23?F/g at scan rates of 5, 10, 20, 50 and 100?mV/s, respectively. Incorporation of LC fibers within MnO₂ nanorods as binders will open the possibilities to fabricate the flexible paper electrode for application in supercapacitors and batteries due to facile synthesis, light-weight and environmentally friendly aspects.     

Synthesis of ZnO rod arrays on aluminum recyclable paper and effect of the rod size on power density of eco-friendly nanogenerators

In this work, we demonstrated a novel and effective approach on the use of low-cost electrodes, an eco-friendly substrate and zinc oxide (ZnO) micro or nanorods (MRs or NRs, respectively) for building triboelectric devices (TENGs). The reported strategy focuses on using low-cost materials and fabrication processes. For the first time and without any pre-treatment, an aluminum recyclable paper from the milk carton (named ARP) was used as a substrate and TENG bottom electrode. A systematic study on the growing of ZnO structures on ARP by chemical bath deposition has been carried out. We found that the ZnO rods size, and resistivity of the TENG upper electrode considerably influence the power density of the device. Such sustainable, low-priced ZnO-based TENGs can produce up to 1.6μW/cm² output power density when operated at 50?Hz. The fabrication of an eco-friendly nanogenerator demonstrates the possibility of manufacturing low-cost, flexible, and large-area energy harvesting devices for future applications.     

纸绳在家具设计中的应用

目的 从绿色家具视角和纸绳家具设计实例出发,探究纸绳家具的设计原则和方法,旨在为实际应用提供一种新的思路.方法 通过对纸绳材料优势的深入分析,结合实例和现阶段绿色家具的设计要求,分析"6R""以人为本"设计原则在纸绳家具设计中的应用,并指导设计实践.结论 "6R"和"以人为本"的设计原则对纸绳家具设计具有指导作用,所设计的纸绳家具不仅能够避免复合纸板家具不耐水、不耐久等不足,也赋予纸家具产品温馨的人文主义气息,达到功能性与艺术性的完美统一.与此同时,在充分了解材料属性的基础上,赋予纸绳家具可回收、再循环和再利用的环保属性,拟满足当代消费者对产品实用性和环保性的双重要求,这对纸材料在家具设计中的进一步拓展具有重要意义.     

超细粉体在复合材料中的功能作用及加工技术

矿物超细粉体作为高性能混凝土、塑料、纸张等复合材料的填充组分，具有降低成本、改善制品性能的作用。论述了矿物超细粉体的功能作用及产生原因和超细粉碎、表面改性技术。     

碎解条件对废旧书刊碎化、油墨剥离和浮选脱墨的影响

研究碎浆条件对废纸脱墨工艺过程的影响。结果表明，废纸脱墨两段碎浆指标较好，两段碎浆浓度都控制在15％～20％脱墨效果显著。碎浆时间对白度影响不大，墨点数在一段和二段碎浆初期出现下降，并且一段碎浆下降急剧，然后两段都趋于缓慢。一、二段碎浆时间分别为20min和10min效果最佳。脱墨剂、水玻璃对灰度影响较大，但对白度影响不大。一、二段脱墨剂和水玻璃最佳用量分别为0．10g／g纸和0．15g／g纸。双氧水对白度影响较大，但对墨点数影响不大。氢氧化钠对脱墨效果影响甚微。废旧书刊纸经过脱墨后，墨点数小于50个／m^2，符合书刊用纸指标。